Argentina winger Di Maria, above, cashed in on Real's dominance but they finished with 10 men after Marcelo was sent off for a second bookable offence.
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Inter Milan, the 2010 champions under Mourinho, suffered a shock 1-0 home defeat by Trabzonspor. Ondrej Celustkas scored for the Turks, who are only in the competition because Fenerbahce were kicked out over a match-fixing scandal.